000 06630cam a22002414a 4500
008 1977
020 _a0070414572
040 _aGAMADERO
_bSPA
_cGAMADERO
041 _aeng
050 0 0 _aQD257
_bMM4
_c1977
100 _aHERBERT MEISLICH
_93987
245 0 0 _aORGANIC CHEMISTRY
250 _a1er.edición
260 3 _aEstados Unidos
_bMcGraw-Hill,Inc
_c1977
300 _a480 pg
_bIlustrado
_c17 cm x 27 cm
505 _aChapter 1 STRUCTURE AND PROPERTIES 1.1 Organic Compounds Chapter 2 BONDING AND MOLECULAR STRUCTURE Atomic Orbitals Covalent Bond Formation-Molecular Orbital (MO) Method Hybridization of Atomic Orbitals Electronegativity and Polarity Oxidation Number Intermolecular (vander Waals) Forces Resonance and Delocalized p Electrons Chapter 3 CHEMICAL REACTIVITY AND ORGANIC REACTIONS 3.1 Reaction Mechanism 3.2 Carbon-Containing Intermediates 3.3 Types of Organic Reactions 3.4 Electrophilic and Nucleophilic Reagents 3.5 Thermodynamics 3.6 Bond Dissociation Energies 3.7 Chemical Equilibrium 3.8 Rates of Reactions 3.9 Transition-State Theory and Enthalpy Diagrams 3.10 Acids and Bases Chapter 4 ALKANES 4.1 Definition 4.2 Nomenclature of Alkanes 4.3 Preparation of Alkanes 4.4 Chemical Properties of Alkanes Chapter 5 STEREOCHEMISTRY 5.1 Stereoisomerism 5.2 Optical Isomerism 5.3 Relative and Absolute Configuration 5.4 Molecules with More than One Chiral Center 5.5 Synthesis and Optical Activity Chapter 6 ALKENES 6.1 Nomenclature and Structure 6.2 Preparation of Alkenes 6.3 Chemical Properties of Alkenes 6.4 Electrophilic Polar Addition Reactions 6.5 Summary of Alkene Chemistry Chapter 7 ALKYL HALIDES 7.1 Introduction 7.2 Synthesis of R 7.3 Chemical Properties 7.4 Summary of Alkyl Halide Chemistry Chapter 8 ALKYNES AND DIENES 8.1 Alkynes 8.2 Chemical Properties of Acetylenes 8.3 Alkadienes 8.4 Polymerization of Dienes 8.5 Summary of Alkyne Chemistry 8.6 Summary of Diene Chemistry Chapter 9 ALICYCLIC COMPOUNDS 9.1Nomenclature and Structure 9.2Methods of Preparation 9.3Conformations of Cycloalkanes Molecular-Orbital Interpretation of Concerted Cycloaddition Reactions: Woodward-Hoffmann Rules 9.5 Terpenes and the Isoprene Rule Chapter 10 BENZENE AND AROMATICITY 10.1 Introduction 10.2 Aromaticity and Hückel's Rule 10.3 Antiaromaticity 10.4 Nomenclature Chapter 11 AROMATIC SUBSTITUTION. ARENES 11.1 Aromatic Substitution by Electrophiles (Lewis Acids, E* or E) 11.2 Nucleophilic and Free-Radical Substitutions 11.3 Arenes Chapter 12 SPECTROSCOPY AND STRUCTURE 12.1 Introduction 12.2 Ultraviolet and Visible Spectroscopy 12.3 Infrared Spectroscopy 12.4 Nuclear Magnetic Resonance 12.5 Mass Spectroscopy Chapter 13 ALCOHOLS 13.1 General 13.2 Preparation 13.3 Reactions of Alcohols Chapter 14 ETHERS, EPOXIDES AND GLYCOLS 14.1 Introduction and Nomenclature 14.2 Preparation 14.3 Chemical Properties 14.4 Glycols 14.5 Summary of Glycol Chemistry Chapter 15 THE CARBONYL COMPOUNDS 15.1 Nomenclature 15.2 Methods of Preparation 15.3 Reactions of Aldehydes and Ketones Chapter 16 CARBOXYLIC ACIDS 16.1 Introduction 16.2 Preparation of Carboxylic Acids 16.3 Reactions of Carboxylic Acids 16.4 Summary of Carboxylic Acid Chemistry 16.5 Analytical Detection of Carboxylic Acids Chapter 17 CARBOXYLIC ACID DERIVATIVES Chapter 18 AMINES 18.1 Introduction and Nomenclature 18.2 Preparation of Amines 18.3 Chemical Properties of Amines 18.4 Spectral Properties 18.5 Reactions of Aryl Diazonium Salts 17.1 Introduction 17.2 Chemistry of Acyl Derivatives 17.3 Dicarboxylic Acid Derivatives 17.4 Claisen Condensation; Reactions of B-Ketoesters 17.5 Lactones, Lactams 17.6 Carbonic Acid Derivatives Chapter 19 ARYL HALIDES 19.1 Introduction 19.2 Reactions of Aryl Halides 19.3 Methods of Preparation of Aryl Halides 19.4 Chemical Properties Chapter 20 AROMATIC SULFONIC ACIDS; ORGANOSULFUR COMPOUNDS 20.1 Introduction 20.2 Preparation 20.3 Chemical Properties 20.4 Derivatives of Aromatic Sulfonic Acids 20.5 Comparison of Sulfonic and Carborvlic Acid Chemistry 20.6 Summary of Aliphatic Sulfur Compounds Chapter 21 PHENOLS 21.1 Introduction 21.2 Preparation 21.3 Chemical Properties 21.4 Analytical Detection of Phenols 21.5 Summary of Phenols 21.6 Summary of Ethers and Esters of Phenols Chapter 22 POLYNUCLEAR AROMATIC HYDROCARBONS 22.1 Introduction 22.2 Isolated Ring Systems 22.3 Naphthalene 22.4 Summary of Naphthalene Reactions Chapter 23 HETEROCYCLIC COMPOUNDS 23.1 Introduction and Nomenclature 23.2 Five-Membered Aromatic Heterocyclic Compounds. Furan (with O), Thiophene (with S), Pyrrole (with N) 23.3 Six-Membered Heterocyclic Compounds 23.4 Condensed Ring Systems Chapter 24 AMINO ACIDS AND PROTEINS 24.1 Introduction 24.2 Preparation of a-Amino Acids 24.3 Acid-Base (Amphoteric) Properties 24.4 Peptides 24.5 Proteins Chapter 25 CARBOHYDRATES 25.1 Introduction 25.2 Chemical Properties of Monosaccharides 25.3 Evidence for Hemiacetal Formation as Exemplified with Glucose 25.4 Stereochemistry of Glucose 25.5 Disaccharides 25.6 Polysaccharides Chapter 26 CHEMICAL CALCULATIONS 26.1 Formulas and Molecular Weights 26.2 Colligative Properties 26.3 Yields 26.4 Neutralization Equivalent (NE) 26.5 Chemical Equilibrium 26.6 Distillation Problems 26.7 Solvent Extraction
520 _aThe beginning student in Organic Chemistry is often overwhelmed by facts, concepts, and new language. Each year, textbooks of Organic Chemistry grow in quantity of subject matter and in level of sophistication. This Schaum'S Outline was undertaken (initially by the senior author, . S.) to give a clear view of first-year Organic Chemistry through the solution of illustrative problems. Completely worked-out problems make up over 80% of the book, the remainder being a concise presentation of theory. The reader learns by thinking and doing rather than by being told. This outline can be used in support of a standard text, as a text to supplement a good set of lecture notes, as a review book for taking professional examinations, and as a vehicle for self-instruction. Our thanks and appreciation to Mr. Larry Alemany for his expert criticism from a student's viewpoint and for his careful proofreading, to Mr. David Beckwith for his editorial assistance, and to Mrs. Joyce Gaiser for her meticulous typing.
526 _aIngenieria en Gestion Empresarial
650 0 _aQuímica
_948
700 _aHOWARD NECHAMKIN
_93989
942 _2ddc
_cLIB
_e1er.edición
_n0
945 _a1260
_bNorma Gabriela Corona Arreguin
_c1260
_dNorma Gabriela Corona Arreguin
999 _c9027
_d9027