TY - BOOK AU - R.T. MORRISON AU - R.N. BOYD TI - STUDY GUIDE TO CHEMISTRY MORRISON AND BOYD SN - 0205044662 AV - QD251.2 M67 PY - 1975/// CY - ESTADOS UNIDOS DE AMERICA PB - A and B KW - QuĂ­mica N1 - IngenierĂ­a Ambiental N2 - Granting that we know the chemistry of the individual steps, how do we go about planning a route to more complicated compounds-alcohols, say? In almost every organic synthesis it is best to begin with the molecule we want the target molecule-and work backwards from it. There are relatively few ways to make a complicated alco-hol, for example; there are relatively few ways to make a Grignard reagent or an alde-hyde or ketone; and so on back to our ultimate starting materials. On the other hand. our starting materials can undergo so many different reactions that, if we go at the prob-lem the other way around, we find a bewildering number of paths, few of which take us where we want to go. We try to limit a synthesis to as few steps as possible, but nevertheless do not sacrifice purity for time. To avoid a rearrangement in the preparation of an alkene, for example, we take two steps via the halide rather than the single step of dehydration ER -