Organic Chemistry

By:

RALPH J. FESSENDEN

Contributor(s):

Joan S. Fessenden

Material type: Text

TextLanguage: Español Publication details: united states willard Grand Press 1982Edition: 2da. ediciónDescription: 228p Ilustración 25.5 x18.5 cmISBN:

0871507536

Subject(s):

Organismos

LOC classification:

QD251.2 F49

Contents:

Chapter 1. Atoms and Molecules - A Review Chapter Chapter Orbitals and Their Role in Covalent Bonding Structural Isomerism, Nomenclature, and Alkanes Chapter 4. Stereochemistry Chapter 5. Alkyl Halides; Substitution and Elimination Reactions Chapter 6. Free-Radical Reactions; Organometallic Compounds Chapter 7. Alcohols, Ethers, and Related Compounds Chapter 8. Spectroscopy I: Infrared and Nuclear Magnetic Resonance Chapter 9. Alkenes and Alkynes Chapter 10. Aromaticity, Benzene, and Substituted Benzenes Chapter 11. Aldehydes and Ketones Chapter 12. Carboxylic Acids Chapter 13. Derivatives of Carboxylic Acids Chapter 14. Enolates and Carbanions: Building Blocks for Organic Synthesis Chapter 15. Amines Chapter 16. Polycyclic and Heterocyclic Aromatic Compounds

Summary: Some Important Features Electrons are found in shells surrounding the nucleus of an atom. Bach shell is composed of one or more atomic orbitals. The first shell contains a ls orbital (spherical); the second shell contains one 2g orbital (spherical) and three 2p orbitals (dumbbell-shaped and mutually perpendicular). Bach orbital can hold zero, one, or two electrons. Electrons are usually contained in the lowest-energy orbitals possible (ls, then 2s, then 2p) - The halogens, oxygen, and nitrogen have fairly high electronegativities (at- traction for outer electrons). The metals have low electronegativities, while carbon and hydrogen have intermediate electronegativities. Chemical bonds are formed by electrons in the outer shell of an atom. Whether ionic or covalent bonds are formed depends on the electronegativity difference between two atoms. Carbon forms covalent bonds with other elements. These covalent bonds may be nonpolar (C-C or C—H) or polar (CO, C-N, or C—Cl), depending on the electronegativity difference between C and the other element. Molecules with NH, OH, or HP bonds can form hydrogen bonds with each other or with other molecules containing N, O, or F atoms with unshared electrons. An acid is a compound that can donate * or accept electrons, while a base is a compound that has unshared electrons that can be donated. Common organic

Holdings
Item type	Current library	Collection	Call number	Copy number	Status	Date due	Barcode
Libro	CI Gustavo A. Madero Sala General	Colección General	QD251.2 F49 1982	EJ.1	Available		03570

Chapter 1. Atoms and Molecules - A Review
Chapter
Chapter
Orbitals and Their Role in Covalent Bonding
Structural Isomerism, Nomenclature, and Alkanes
Chapter 4. Stereochemistry
Chapter 5. Alkyl Halides; Substitution and Elimination Reactions Chapter 6. Free-Radical Reactions; Organometallic Compounds
Chapter 7. Alcohols, Ethers, and Related Compounds
Chapter 8. Spectroscopy I: Infrared and Nuclear Magnetic
Resonance
Chapter 9. Alkenes and Alkynes
Chapter 10.
Aromaticity, Benzene, and Substituted Benzenes
Chapter 11. Aldehydes and Ketones
Chapter 12. Carboxylic Acids
Chapter 13.
Derivatives of Carboxylic Acids
Chapter 14. Enolates and Carbanions: Building Blocks for
Organic Synthesis
Chapter 15. Amines
Chapter 16. Polycyclic and Heterocyclic Aromatic Compounds

Some Important Features
Electrons are found in shells surrounding the nucleus of an atom.
Bach shell is
composed of one or more atomic orbitals. The first shell contains a ls orbital (spherical); the second shell contains one 2g orbital (spherical) and three 2p orbitals (dumbbell-shaped and mutually perpendicular). Bach orbital can hold zero, one, or two electrons.
Electrons are usually contained in the lowest-energy
orbitals possible (ls, then 2s, then 2p) -
The halogens, oxygen, and nitrogen have fairly high electronegativities (at-
traction for outer electrons). The metals have low electronegativities, while carbon and hydrogen have intermediate electronegativities.
Chemical bonds are formed by electrons in the outer shell of an atom.
Whether ionic or covalent bonds are formed depends on the electronegativity difference between two
atoms. Carbon forms covalent bonds with other elements. These
covalent bonds may be nonpolar (C-C or C—H) or polar (CO, C-N, or C—Cl), depending on the electronegativity difference between C and the other element.
Molecules with NH, OH, or HP bonds can form hydrogen bonds with each other
or with other molecules containing N, O, or F atoms with unshared electrons.
An acid is a compound that can donate * or accept electrons, while a base
is a compound that has unshared electrons that can be donated. Common organic

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